20070623

Turning Whole Plants into Fuel in Four Simple Steps

A new process can turn plants into energy-dense fuel by combining the power of fermentation and chemical reactions.A recipe for fuel: take the carbohydrates like starch and cellulose that make up the majority of plants. Use enzymes to break them down into fructose, the sugar found in fruits and honey. Mix this fructose with salt water and hydrochloric acid. Add a solvent—in this case butanol also derived from plant matter—to protect the resulting hydroxymethylfurfural (HMF) from reacting with the water, then extract it. This versatile molecule can be used to create plastic polymers or other chemicals. And by the way, adding a copper-coated ruthenium catalyst can also convert the HMF to DMF (2,5-dimethylfuran), a fuel that provides more energy than ethanol."It should be a great fuel," says James Dumesic, a chemical engineer at the University of Wisconsin–Madison, who, along with his colleagues, discovered the new process, "DMF has the energy density of petroleum."



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